Oxygen ion displacement in compositionally homogeneous, nanocrystalline ZrO2-12 mol% Y2O3 powders

被引:13
作者
Lamas, DG [1 ]
de Reca, NEW [1 ]
机构
[1] UNSAM, CONICET, CITEFA, PRINSO, RA-1603 Buenos Aires, DF, Argentina
关键词
zirconia-yttria; nanocrystalline powders; oxygen displacement; X-ray diffraction; Rietveld analysis;
D O I
10.1016/S0167-577X(99)00131-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The crystal structure of compositionally homogeneous, nanocrystalline ZrO2-12 mol% Y2O3 powders was studied by X-ray diffraction. By applying the Rietveld method, it was found that these powders present a tetragonal phase with an axial ratio of unity, but with the oxygen ions displaced from their ideal fluorite positions along the c-axis (t "-form of the tetragonal phase). The influence of the crystallite size on the oxygen ion displacement was also studied. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:204 / 208
页数:5
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