A double INHIBIT logic gate employing configuration and fluorescence changes

被引:133
作者
Qu, Da-Hui
Ji, Feng-Yuan
Wang, Qiao-Chun
Tian, He [1 ]
机构
[1] E China Univ Sci & Technol, Lab Adv Mat, Shanghai 200237, Peoples R China
[2] E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China
关键词
D O I
10.1002/adma.200600235
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A lockable as well as double INHIBIT logic gate based on a [2]rotaxane employing configuration and fluorescence changes has been demonstrated (see figure). Importantly, the output "0" and "1" states of the current logic circuits represent several different supramolecular configurations. The photoisomerization process is completely reversible, making the shuttling motions of the cyclodextrin ring repeatable and accompanied by a reversible florescence signal.
引用
收藏
页码:2035 / 2038
页数:4
相关论文
共 44 条
[1]   Molecule-based photonically switched half-adder [J].
Andréasson, J ;
Kodis, G ;
Terazono, Y ;
Liddell, PA ;
Bandyopadhyay, S ;
Mitchell, RH ;
Moore, TA ;
Moore, AL ;
Gust, D .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (49) :15926-15927
[2]  
Balzani V, 2000, ANGEW CHEM INT EDIT, V39, P3348, DOI 10.1002/1521-3773(20001002)39:19<3348::AID-ANIE3348>3.0.CO
[3]  
2-X
[4]  
Balzani V., 2003, Molecular Devices and Machines, a Journey into the Nanoworld
[5]   Photoinduction of fast, reversible translational motion in a hydrogen-bonded molecular shuttle [J].
Brouwer, AM ;
Frochot, C ;
Gatti, FG ;
Leigh, DA ;
Mottier, L ;
Paolucci, F ;
Roffia, S ;
Wurpel, GWH .
SCIENCE, 2001, 291 (5511) :2124-2128
[6]   Information storage using supramolecular surface patterns [J].
Cavallini, M ;
Biscarini, F ;
Léon, S ;
Zerbetto, F ;
Bottari, G ;
Leigh, DA .
SCIENCE, 2003, 299 (5606) :531-531
[7]   Electronically configurable molecular-based logic gates [J].
Collier, CP ;
Wong, EW ;
Belohradsky, M ;
Raymo, FM ;
Stoddart, JF ;
Kuekes, PJ ;
Williams, RS ;
Heath, JR .
SCIENCE, 1999, 285 (5426) :391-394
[8]   Shuttles and muscles:: Linear molecular machines based on transition metals [J].
Collin, JP ;
Dietrich-Buchecker, C ;
Gaviña, P ;
Jimenez-Molero, MC ;
Sauvage, JP .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (06) :477-487
[9]   Logic operations at the molecular level. An XOR gate based on a molecular machine [J].
Credi, A ;
Balzani, V ;
Langford, SJ ;
Stoddart, JF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (11) :2679-2681
[10]   Molecular-scale logic gates [J].
de Silva, AP ;
McClenaghan, ND .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (03) :574-586