High-energy X-ray structure determinations using synchrotron radiation -: Part 3.: Self-assembly of a lacunary α-Keggin undecatungstophosphate into a three-dimensional network linked by s-block cations

被引：51

作者：

Honma, N

Kusaka, K

Ozeki, T

机构：

[1] Tokyo Inst Technol, Dept Chem & Mat Sci, Meguro Ku, Tokyo 1528551, Japan

[2] Japan Sci & Technol Corp, CREST, Kawaguchi, Saitama 3320012, Japan

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 23期

关键词：

D O I：

10.1039/b209076g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of [(CH3)(4)N](4)Na2H[alpha-PW11O39].8H(2)O has been determined by using the Weissenberg camera at the BL04B2 beamline of SPring-8, revealing that it contains a disorder-free lacunary [alpha-PW11O39](7-) anion with one sodium cation embedded into its lacuna that links the oxometalate building blocks into a one-dimensional chain, which is then woven into a three-dimensional latticework by another Na+.

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页码：2896 / 2897

页数：2

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