Cobalt-catalyzed Heck-type reaction of alkyl halides with styrenes

被引：232

作者：

Ikeda, Y ^{[1
]}

Nakamura, T ^{[1
]}

Yorimitsu, H ^{[1
]}

Oshima, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Mat Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 23期

关键词：

D O I：

10.1021/ja026296l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equqtion Presentation) A cobalt complex, CoCl2[1,6-bis(diphenylphosphino)hexane], catalyzes an alkylation reaction of styrenes in the presence of Me3SiCH2MgCl in ether to yield β-alkylstyrenes. A variety of alkyl halides including alkyl chlorides can be employed as an alkyl source. A radical mechanism is strongly suggested for this alkylation reaction. Copyright © 2002 American Chemical Society.

引用

页码：6514 / 6515

页数：2

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