Almost perfect enantio-differentiating hydrogenation of methyl 3-cyclopropyl-3-oxopropanoate over tartaric acid modified Raney nickel catalyst

被引：36

作者：

Nakagawa, S ^{[1
]}

Sugimura, T ^{[1
]}

Tai, A ^{[1
]}

机构：

[1] HIMEJI INST TECHNOL, FAC SCI, KAMIGORI, HYOGO 67812, JAPAN

来源：

CHEMISTRY LETTERS | 1997年 / 09期

关键词：

D O I：

10.1246/cl.1997.859

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Almost perfect enantio-differentiating hydrogenation was achieved by asymmetrically modified heterogeneous catalyst. The hydrogenation of methyl 3-cyclopropyl-3-oxopropanoate over tartaric acid modified Raney nickel gave methyl 3-cyclopropyl-3-hydroxypropanoate in more than 98% of optical purity.

引用

页码：859 / 860

页数：2

共 11 条

[1] STUDIES ON MODIFIED HYDROGENATION CATALYST .3. ASYMMETRIC HYDROGENATION WITH MODIFIED RANEY NICKEL .2. [J].

IZUMI, Y ;

IMAIDA, M ;

FUKAWA, H ;

AKABORI, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1963, 36 (02) :155-160

[2] MODIFIED RANEY-NICKEL (MRNI) CATALYST - HETEROGENEOUS ENANTIO-DIFFERENTIATING (ASYMMETRIC) CATALYST [J].

IZUMI, Y .

ADVANCES IN CATALYSIS, 1983, 32 :215-271

[3] METHODS OF ASYMMETRIC SYNTHESIS - ENANTIOSELECTIVE CATALYTIC HYDROGENATION [J].

IZUMI, Y .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1971, 10 (12) :871-&

[4]

Rappoport Z., 1987, CHEM CYCLOPROPYL GRO, V1

[5]

Rappoport Z., 1987, CHEM CYCLOPROPYL GRO, V2

[6]

SACHTLER WMH, 1985, CHEM IND, V22, P189

[7] PREPARATION OF OPTICALLY PURE (3S,5S)-2,6-DIMETHYL-3,5-HEPTANEDIOL AND (3R,5R)-2,6-DIMETHYL-3,5-HEPTANEDIOL [J].

SUGIMURA, T ;

YOSHIKAWA, M ;

YONEDA, T ;

TAI, A .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (04) :1080-1082

[8]

Sugimura T, 1996, STUD SURF SCI CATAL, V101, P231

[9] AN IMPROVED ASYMMETRICALLY-MODIFIED NICKEL-CATALYST PREPARED FROM ULTRASONICATED RANEY-NICKEL [J].

TAI, A ;

KIKUKAWA, T ;

SUGIMURA, T ;

INOUE, Y ;

ABE, S ;

OSAWA, T ;

HARADA, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1994, 67 (09) :2473-2477

[10]

TAI A, 1986, TAILORED METAL CATAL, P265

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