A redox-active C3-symmetric triindole-based triazacyclophane

被引：46

作者：

Gomez-Lor, Berta ^{[1
]}

Hennrich, Gunther

Alonso, Beatriz

Monge, Angeles

Gutierrez-Puebla, Enrique

Echavarren, Antonio M.

机构：

[1] Inst Ciencia Mat, E-20849 Madrid, Spain

[2] Inst Chem Res Catalonia ICIQ, E-43007 Tarragona, Spain

[3] Univ Autonoma Madrid, Dept Quim Organ, Dept Quim Inorgan, E-20849 Madrid, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 27期

关键词：

charge transfer; cyclophanes; heterocycles; oxidation; radical ions;

D O I：

10.1002/anie.200600526

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Spreading the charge: The highly stable dimeric radical cation of a C3-symmetric triazacyclophane (see picture), with the positive charge delocalized over the two molecules, offers an excellent model for the study of intermolecular communication depending on hole hopping. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4491 / 4494

页数：4

共 43 条

[1] Radical ions from 3,3′′′,3′′′′-tris(butylsulfanyl)-2,2′:5′,2":5",2′′′,5′′′,2′′′′:5′′′′,2′′′′′-sexithiophene:: An experimental and theoretical study of the p- and n-doped oligomer [J].