In-situ UV-visible study of Pd nanocluster formation in solution

被引：59

作者：

Gaikwad, Anil V. ^{[1
]}

Rothenberg, Gadi ^{[1
]}

机构：

[1] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1018 WV Amsterdam, Netherlands

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2006年 / 8卷 / 31期

关键词：

C-C; SPECTROSCOPIC ANALYSIS; HOMOGENEOUS CATALYSIS; COUPLING REACTIONS; METAL; MECHANISM; GROWTH; GOLD; NANOPARTICLES; NUCLEATION;

D O I：

10.1039/b604665g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The formation of Pd nanoclusters in solution is studied. This system has two types of light-absorbing species: Pd ions which absorb light via electronic transitions and Pd clusters and aggregates which absorb light via valence-conduction transitions and also scatter light due to their nanometric dimensions. Here we monitor these dynamic changes using UV-visible spectroscopy. The reduction and clustering concentration profiles are extracted from the raw data using a combination of net analyte signal (NAS) and principal component analysis (PCA) methods. PdCl2, Pd(OAC)(2) and Pd(NO3)(2) are used as Pd2+ precursors and various tetra-noctylammonium carboxylates are applied as reducing and stabilising agents. This in situ approach enables the quantification of both the reduction of the Pd2+ ions and the growth of the Pd clusters. Kinetic models that account for ion reduction, cluster growth and aggregation are presented and the influence of the counteranions and the reducing agents on these processes is discussed.

引用

页码：3669 / 3675

页数：7

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