Combined redox couples for catalytic oxidation of methane by dioxygen at low temperatures

被引：112

作者：

an, Zengji An ^{[1
]}

Pan, Xiulian ^{[1
]}

Liu, Xiumei ^{[1
]}

Han, Xiuwen ^{[1
]}

Bao, Xinhe ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 50期

关键词：

D O I：

10.1021/ja0647912

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The combination of three redox couples Pd2+/Pd0-quinone/hydroquinone-NO2/NO creates an electron-transfer loop, which facilitates one-pot catalytic oxidation of methane selectively to methanol by dioxygen in CF3COOH at a temperature as low as 80 °C. This is the first example where an organic cocatalyst significantly increases the catalytic efficiency of a transition metal in the selective oxidation of methane in the presence of dioxygen. Copyright © 2006 American Chemical Society.

引用

页码：16028 / 16029

页数：2

共 16 条

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