Synthesis of optically active allenes using tandem enzyme and palladium-catalysed reactions

被引：64

作者：

Dixneuf, PH ^{[1
]}

Guyot, T ^{[1
]}

Ness, MD ^{[1
]}

Roberts, SM ^{[1
]}

机构：

[1] UNIV LIVERPOOL,DEPT CHEM,LIVERPOOL L69 7ZD,MERSEYSIDE,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 21期

关键词：

D O I：

10.1039/a704374k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The propargylic carbonates (S)-6 and (R)-9 are converted into the chiral allenes 10, 11, 13 and 14 (ee 82-85%) using organozinc reagents and tetrakis(triphenylphosphine) palladium as catalyst.

引用

页码：2083 / 2084

页数：2

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