Scattering of vibrationally and electronically excited CO molecules from a LiF(100) surface

被引：14

作者：

Jongma, RT ^{[1
]}

Berden, G ^{[1
]}

Rasing, T ^{[1
]}

Zacharias, H ^{[1
]}

Meijer, G ^{[1
]}

机构：

[1] UNIV MUNSTER,INST PHYS,D-48149 MUNSTER,GERMANY

来源：

CHEMICAL PHYSICS LETTERS | 1997年 / 273卷 / 3-4期

关键词：

D O I：

10.1016/S0009-2614(97)00592-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Experiments are performed in which vibrationally and electronically excited CO(a(3) Pi, v=1) molecules are scattered from a LiF(100) surface. As there is originally no population in the vibrationless level of the metastable state, this experiment gives the unique possibility of probing the vibrationally inelastic channel in the scattering of vibrationally excited molecules. The vibrational deactivation probability can thus be accurately determined and is found to be below 10(-3) for the system under study. (C) 1997 Elsevier Science B.V.

引用

页码：147 / 152

页数：6

共 24 条

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[Anonymous], 1969, ROTATIONAL STRUCTURE

[2] The structure of the third positive group of CO bands [J].