Synthesis and crystal structure of [{nBuMg(μ-TMP)}2] and of a homometallic inverse crown in tetranuclear [{nBuMg2[μ-N(H)Dipp]2(μ3-OnBu)}2]

被引：30

作者：

Hevia, E ^{[1
]}

Kennedy, AR ^{[1
]}

Mulvey, RE ^{[1
]}

Weatherstone, S ^{[1
]}

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 13期

关键词：

alkoxides; amides; crown compounds; inverse crown compounds; magnesium;

D O I：

10.1002/anie.200353286

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Previous inverse crown amides have been heterometallic compounds that contain a mixture of alkali-metal ions (M+) and magnesium cations. However, the first homometallic (magnesium-magnesium′) inverse crown is unveiled (see picture) by exploiting the isovalent relationship between M + and (BuMg)+.

引用

页码：1709 / 1712

页数：4

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