Reaction monitoring of polyaniline film formation on carbon nanotubes with TOF-SIMS

被引:13
作者
Chen, WY [1 ]
Chen, CY [1 ]
Hsu, KY [1 ]
Wang, CC [1 ]
Ling, YC [1 ]
机构
[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan
关键词
polyaniline; carbon nanotubes; surface modification; TOF-SIMS;
D O I
10.1016/j.apsusc.2004.03.139
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A polyaniline (PANT) film was successfully prepared on multiwall carbon nanotubes (CNTs) by modifying the CNTs with aromatic amine group (CNTs-(NC6H6)(n)) followed by aniline polymerization. TOF-SIMS was used to monitor C6H6N-, C2H3Cl-, C8H- and C-10(-) to reveal the interfacial change at PANT film/CNTs-(NC6H6)(n). The functionalized group of CNTs modified with aniline was determined to be C6H6N-, which showed positive effect on polymerization of aniline as shown by the TOF-SIMS ion image. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:845 / 849
页数:5
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