Intracluster hydrogen transfer followed by dissociation in the phenol-(NH3)3 excited state:: PhOH(S1)-(NH3)3→PhO•+(NH4)(NH3)2

被引：82

作者：

Pino, GA ^{[1
]}

Dedonder-Lardeux, C ^{[1
]}

Grégoire, G ^{[1
]}

Jouvet, C ^{[1
]}

Martrenchard, S ^{[1
]}

Solgadi, D ^{[1
]}

机构：

[1] Univ Paris Sud, CNRS, Photophys Mol Lab, F-91405 Orsay, France

来源：

JOURNAL OF CHEMICAL PHYSICS | 1999年 / 111卷 / 24期

关键词：

D O I：

10.1063/1.480437

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The study of the phenol-(NH3)(3) cluster with two-color two-photon ionization shows that the main ion observed with delays between the lasers up to a few hundred nanoseconds is the (NH4)(+)(NH3)(2) fragment, resulting from direct ionization of the (NH4)(NH3)(2) product coming from the reaction: PhOH(S-1)-(NH3)(3)--> PhO.+(NH4)(NH3)(2). (C) 1999 American Institute of Physics. [S0021-9606(99)01448-8].

引用

页码：10747 / 10749

页数：3

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