Kinetics of formation of dihydrogen complexes by protonation of CpRuHL complexes (L = DPPM, DPPE, 2 PPh3) with HBF4•Et2O in THF and the failure to observe dihydrogen complexes in the reactions with other acids

被引：17

作者：

Basallote, MG ^{[1
]}

Durán, J ^{[1
]}

Fernández-Trujillo, MJ ^{[1
]}

Máñez, MA ^{[1
]}

机构：

[1] Univ Cadiz, Fac Ciencias, Dept Ciencia Mat & Ingn Met & Quim Inorgan, Cadiz 11510, Spain

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 04期

关键词：

D O I：

10.1021/om9907775

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The second-order rate constants for the reactions of the title complexes with HBF4 in THF do not correlate with the previously reported pK(a)'s of these complexes. The lack of formation of dihydrogen complexes in their reactions with HCl, HBr, or CF3COOH in THF and acetone solutions indicates the limited validity of predictions based on aqueous pK(a) scales.

引用

页码：695 / 698

页数：4

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