Uranyl Diphosphonates with Pillared Structures

被引：53

作者：

Adelani, Pius O.

Albrecht-Schmitt, Thomas E. ^{[1
]}

机构：

[1] Univ Notre Dame, Dept Civil Engn & Geol Sci, Notre Dame, IN 46556 USA

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 07期

关键词：

POWDER DIFFRACTION DATA; CATALYZED TRANSFORMATION; CRYSTAL-STRUCTURES; PHENYLPHOSPHONATE; PHOSPHONATES; PHOSPHATE;

D O I：

10.1021/ic900172s

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学];

摘要：

A series of five uranyl diphosphonates with pillared and canted pillared structures have been prepared and characterized. These compounds are constructed from UO6 tetragonal bipyramids and UO7 pentagonal bipyramids that are bridged by the diphosphonate anions. All of these compounds fluoresce at room temperature.

引用

收藏

页码：2732 / 2734

页数：3

相关论文

共 16 条

[1]

Polymorphism and phase transition in nanotubular uranyl phenylphosphonate:: (UO2)3(HO3PC6H5)2(O3PC6H5)2•H2O [J].

Aranda, MAG ;

Cabeza, A ;

Bruque, S ;

Poojary, DM ;

Clearfield, A .

INORGANIC CHEMISTRY, 1998, 37 (08) :1827-1832

[2]

THE STRUCTURE OF THE URANYL HYDROXYMETHYLPHOSPHONATE PENTAHYDRATE COMPLEXES [J].

BRITEL, A ;

WOZNIAK, M ;

BOIVIN, JC ;

NOWOGROCKI, G ;

THOMAS, D .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1986, 42 :1502-1505

[3]

Synthesis, structure and characterization of uranium(IV) phenyl phosphonate, U(O3PC6H5)(2), and uranium(IV) pyro phosphate, UP2O7 [J].

Cabeza, A ;

Aranda, MAG ;

Cantero, FM ;

Lozano, D ;

MartinezLara, M ;

Bruque, S .

JOURNAL OF SOLID STATE CHEMISTRY, 1996, 121 (01) :181-189

[4]

ZEOLITE AND MOLECULAR-SIEVE SYNTHESIS [J].

DAVIS, ME ;

LOBO, RF .

CHEMISTRY OF MATERIALS, 1992, 4 (04) :756-768

[5]

Denning RG, 1980, ACS SYM SER, V131

[6]

Reactant-mediated diversity in uranyl phosphonates [J].

Doran, MB ;

Norquist, AJ ;

O'Hare, D .

CHEMISTRY OF MATERIALS, 2003, 15 (07) :1449-1455

[7]

Alkali-ion-catalyzed transformation of two linear uranyl phosphonates into a tubular one [J].

Grohol, D ;

Clearfield, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (39) :9301-9302

[8]

Syntheses and crystal structures of a linear-chain uranyl phenylphosphinate UO2(O2PHC6H5)2 and layered uranyl methylphosphonate UO2(O3PCH3) [J].

Grohol, D ;

Gingl, F ;

Clearfield, A .

INORGANIC CHEMISTRY, 1999, 38 (04) :751-756

[9]

Solid-state water-catalyzed transformation at room temperature of a nonluminescent linear-chain uranyl phenylphosphonate into a luminescent one [J].

Grohol, D ;

Clearfield, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (20) :4662-4668

[10]

Synthesis, crystal structures, and proton conductivity of two linear-chain uranyl phenylphosphonates [J].

Grohol, D ;

Subramanian, MA ;

Poojary, DM ;

Clearfield, A .

INORGANIC CHEMISTRY, 1996, 35 (18) :5264-5271