What do titano- and zirconocenes do with diynes and polyynes?

被引：240

作者：

Rosenthal, U ^{[1
]}

Pellny, PM ^{[1
]}

Kirchbauer, FG ^{[1
]}

Burlakov, VV ^{[1
]}

机构：

[1] Univ Rostock, Inst Organ Katalyseforsch, D-18055 Rostock, Germany

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2000年 / 33卷 / 02期

关键词：

D O I：

10.1021/ar9900109

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A thorough investigation of the reactions of diynes, R(C=C)(2)R, and polyynes, R(C=C),R, with titanocene and zirconocene was performed using the metallocene sources Cp2M(C)(eta(2)-Me3SiC=CSiMe3) (M = Ti, L = -; M = Zr, L = THF, pyridine). The conversions show an array of different products generated in complexation, coupling, and cleavage reactions. These results include remarkable structures (e.g., five-membered metallacyclocumulenes) and reactions (e.g., C-C single-bond cleavage). In addition, the first C-C single-bond metathesis in homogeneous solution was discovered. The presented findings have been supported by theoretical studies.

引用

页码：119 / 129

页数：11

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