Enhanced visible light photocatalytic activity of Zn2SnO4 Via sulfur anion-doping

被引:51
作者
Lin, Yuexu [1 ,2 ]
Lin, Shen [1 ,2 ]
Luo, Minghong [1 ]
Liu, Jiaohua [1 ]
机构
[1] Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China
[2] Fuzhou Univ, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Peoples R China
关键词
Zn2SnO4; Sulfur doping; Interstitial doping; Visible light photocatalytic activity; TITANIUM-DIOXIDE; TIO2; DEGRADATION; OXIDES;
D O I
10.1016/j.matlet.2009.02.020
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Sulfur anion doped Zn2SnO4 was prepared by calcining the mixture of thiourea and spinel Zn2SnO4 at 300 degrees C under argon atmosphere and characterized by XRD, XPS and DRS. It was found that S2- was incorporated interstitially into the bulk phase of Zn2SnO4. After the doping of S2-, the band gap of Zn2SnO4 Was sharply decreased to 2.7 eV compared with that of uncloped Zn2SnO4 (-3.6 eV). The photocatalytic activity of S-doped Zn2SnO4 was enhanced for photoclegraclation of Rhodamine B (RhB) in aqueous solution under visible light irradiation. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1169 / 1171
页数:3
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