Electrochemical properties of lithium vanadium phosphate as a cathode material for lithium-ion batteries

被引：240

作者：

Saïdi, MY ^{[1
]}

Barker, J ^{[1
]}

Huang, H ^{[1
]}

Swoyer, JL ^{[1
]}

Adamson, G ^{[1
]}

机构：

[1] Valence Technol Inc, Henderson, NV 89015 USA

来源：

ELECTROCHEMICAL AND SOLID STATE LETTERS | 2002年 / 5卷 / 07期

关键词：

D O I：

10.1149/1.1479295

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The properties of the monoclinic lithium vanadium phosphate Li3V2 (PO4)(3) are investigated using X-ray diffraction (XRD) and electrochemical methods. Electrochemical measurements conducted in half-cells with Li3V2 (PO4)(3) as the cathode material and lithium metal as the anode have shown that this material exhibits an excellent reversibility when the charge extracted is confined to that equivalent to two lithiums per formula unit. The extraction of the last lithium is observed at a potential greater than 4.6 V vs. Li/Li+ and involves a significant overvoltage. Upon discharge, however, XRD has shown that the original structure is recovered. (C) 2002 The Electrochemical Society.

引用

页码：A149 / A151

页数：3

共 17 条

[1] [Anonymous], [No title captured]
[2] Armand M. B., 1980, Materials for Advanced Batteries. Proceedings of a NATO Symposium on Materials for Advanced Batteries, P145
[3] AN ELECTROCHEMICAL INVESTIGATION OF THE DOPING PROCESSES IN POLY(THIENYLENE VINYLENE)
BARKER, J
[J]. SYNTHETIC METALS, 1989, 32 (01) : 43 - 50
[4] SUPERIONIC CONDUCTORS LI3FE2(PO4)3, LI3SC2(PO4)3, LI3CR2(PO4)3 - SYNTHESIS, STRUCTURE AND ELECTROPHYSICAL PROPERTIES
BYKOV, AB
CHIRKIN, AP
DEMYANETS, LN
DORONIN, SN
GENKINA, EA
IVANOVSHITS, AK
KONDRATYUK, IP
MAKSIMOV, BA
MELNIKOV, OK
MURADYAN, LN
SIMONOV, VI
TIMOFEEVA, VA
[J]. SOLID STATE IONICS, 1990, 38 (1-2) : 31 - 52
[5] V2(PO4)3 - A NOVEL NASICON-TYPE VANADIUM PHOSPHATE SYNTHESIZED BY OXIDATIVE DEINTERCALATION OF SODIUM FROM NA3V2(PO4)3
GOPALAKRISHNAN, J
RANGAN, KK
[J]. CHEMISTRY OF MATERIALS, 1992, 4 (04) : 745 - 747
[6] JACOBSEN T, 1979, J ELECTROCHEM SOC, V126, P608
[7] KOKKOROS PA, 1965, MINERAL PETROGR MITT, V10, P45
[8] Cathode materials for lithium rocking chair batteries
Koksbang, R
Barker, J
Shi, H
Saidi, MY
[J]. SOLID STATE IONICS, 1996, 84 (1-2) : 1 - 21
[9] LITHIUM-ION RECHARGEABLE BATTERIES
MEGAHED, S
SCROSATI, B
[J]. JOURNAL OF POWER SOURCES, 1994, 51 (1-2) : 79 - 104
[10] MORGAN D, UNPUB

← 1 2 →