Integrating single-wall carbon nanotubes into donor-acceptor nanohybrids

被引：220

作者：

Guldi, DM ^{[1
]}

Rahman, GMA

Jux, N

Tagmatarchis, N

Prato, M

机构：

[1] Univ Erlangen Nurnberg, Inst Phys & Theoret Chem, D-91058 Erlangen, Germany

[2] Univ Notre Dame, Radiat Lab, Notre Dame, IN 46556 USA

[3] Univ Erlangen Nurnberg, Inst Organ Chem, D-91058 Erlangen, Germany

[4] Univ Trieste, Dipartimento Sci Farmaceut, I-34127 Trieste, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 41期

关键词：

carbon nanotubes; donor-acceptor systems; electron transfer; porphyrinoids; zinc;

D O I：

10.1002/anie.200461217

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A tube for electrons: Through π-π and Coulomb interactions, a complex is obtained between carbon nanotubes grafted with pyrene+ (1) and the zinc porphyrin complex 2. Photoexcitation of the resulting donor-acceptor assembly is followed by a rapid and efficient charge separation to generate a charge-separated state that lives for microseconds.

引用

页码：5526 / 5530

页数：5

共 29 条

[1] Covalent chemistry of single-wall carbon nanotubes
Bahr, JL
Tour, JM
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (07) : 1952 - 1958
[2] Electrostatic assemblies of fullerene-porphyrin hybrids: Toward long-lived charge separation
Balbinot, D
Atalick, S
Guldi, DM
Hatzimarinaki, M
Hirsch, A
Jux, N
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (48) : 13273 - 13279
[3] BALZANI V, 1992, NATO ASI SERIES
[4] Rational chemical strategies for carbon nanotube functionalization
Banerjee, S
Kahn, MGC
Wong, SS
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (09) : 1899 - 1908
[5] PHOTOSYNTHESIS - ELECTRON-TRANSFER THEORY IN QUESTION
BARBER, J
[J]. NATURE, 1988, 333 (6169) : 114 - 114
[6] Noncovalent sidewall functionalization of single-walled carbon nanotubes for protein immobilization
Chen, RJ
Zhang, YG
Wang, DW
Dai, HJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (16) : 3838 - 3839
[7] DRESSELAHUS MS, 2001, CARBON NANOTUBES SYN
[8] Overcoming the insolubility of carbon nanotubes through high degrees of sidewall functionalization
Dyke, CA
Tour, JM
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (04) : 813 - 817
[9] Organic functionalization of carbon nanotubes
Georgakilas, V
Kordatos, K
Prato, M
Guldi, DM
Holzinger, M
Hirsch, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (05) : 760 - 761
[10] Multicomponent redox gradients on photoactive electrode surfaces
Guldi, DM
Zilbermann, I
Anderson, G
Li, A
Balbinot, D
Jux, N
Hatzimarinaki, M
Hirsch, A
Prato, M
[J]. CHEMICAL COMMUNICATIONS, 2004, (06) : 726 - 727

← 1 2 3 →