Thienyl carboxylate ligands bound to M2 quadruple bonds involving molybdenum and tungsten.: Models for dimetallated polythiophenes

被引:18
作者
Byrnes, MJ [1 ]
Chisholm, MH [1 ]
机构
[1] Ohio State Univ, Dept Chem, Newman & Wolfrom Lab, Columbus, OH 43210 USA
关键词
D O I
10.1039/b205082j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Thienyl-carboxylate and -dicarboxylate groups attached to dinuclear centers (M = Mo or W) having MM quadruple bonds show interesting electronic properties and provide insight into the probable nature of related dimetallated polythiophenes.
引用
收藏
页码:2040 / 2041
页数:2
相关论文
共 13 条
[1]  
BRIGNOLE AB, 1971, INORG SYNTH, V13, P81
[2]   Oxalate-bridged complexes of dimolybdenum and ditungsten supported by pivalate ligands:: (tBuCO2)3M2(μ-O2CCO2)M2(O2CtBu)3.: Correlation of the solid-state, molecular, and electronic structures with Raman, resonance Raman, and electronic spectral data [J].
Bursten, BE ;
Chisholm, MH ;
Clark, RJH ;
Firth, S ;
Hadad, CM ;
MacIntosh, AM ;
Wilson, PJ ;
Woodward, PM ;
Zaleski, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (12) :3050-3063
[3]   M2 δ-to-oxalate π* conjugation in oxalate-bridged complexes containing M-M quadruple bonds [J].
Bursten, BE ;
Chisholm, MH ;
Hadad, CM ;
Li, J ;
Wilson, PJ .
CHEMICAL COMMUNICATIONS, 2001, (22) :2382-2383
[4]   METAL METAL MULTIPLE BONDS IN ORDERED ASSEMBLIES .1. TETRANUCLEAR MOLYBDENUM AND TUNGSTEN CARBOXYLATES INVOLVING COVALENTLY LINKED M-M QUADRUPLE BONDS - MOLECULAR-MODELS FOR SUBUNITS OF ONE-DIMENSIONAL STIFF-CHAIN POLYMERS [J].
CAYTON, RH ;
CHISHOLM, MH ;
HUFFMAN, JC ;
LOBKOVSKY, EB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (23) :8709-8724
[5]   On the electron delocalization in the radical cations formed by oxidation of MM quadruple bonds linked by oxalate and perfluoroterephthalate bridges [J].
Chisholm, MH ;
Pate, BD ;
Wilson, PJ ;
Zaleski, JM .
CHEMICAL COMMUNICATIONS, 2002, (10) :1084-1085
[6]  
Cotton F.A., 1993, MULTIPLE BONDS METAL
[7]   SYNTHESIS AND OPTICAL SPECTROSCOPY OF LINEAR LONG-CHAIN DI-TERMINAL ALKYNES AND THEIR PT-SIGMA-ACETYLIDE POLYMERIC COMPLEXES [J].
KHAN, MS ;
KAKKAR, AK ;
LONG, NJ ;
LEWIS, J ;
RAITHBY, P ;
NGUYEN, P ;
MARDER, TB ;
WITTMANN, F ;
FRIEND, RH .
JOURNAL OF MATERIALS CHEMISTRY, 1994, 4 (08) :1227-1232
[8]   ORGANOMETALLIC COMPOUNDS FOR NONLINEAR OPTICS - THE SEARCH FOR EN-LIGHT-ENMENT [J].
LONG, NJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (01) :21-38
[9]   Organometallic polymers with transition metals in the main chain [J].
Nguyen, P ;
Gómez-Elipe, P ;
Manners, I .
CHEMICAL REVIEWS, 1999, 99 (06) :1515-1548
[10]   METAL METAL BONDED COMPLEXES OF THE EARLY TRANSITION-METALS .9. SYNTHESIS AND PROPERTIES OF DITUNGSTEIN(II) TETRACARBOXYLATES [J].
SANTURE, DJ ;
HUFFMAN, JC ;
SATTELBERGER, AP .
INORGANIC CHEMISTRY, 1985, 24 (03) :371-378