Rational design and control of the dimensions of channels in three-dimensional, porous metal-organic frameworks constructed with predesigned hexagonal layers and pillars

被引:93
作者
Li, Cui-Jin
Hu, Sheng
Li, Wei
Lam, Chi-Keung
Zheng, Yan-Zhen
Tong, Ming-Liang [1 ]
机构
[1] Sun Yat Sen Univ, State Key Lab Optoelect Mat & Technol, Inst Optoelect & Funct Composite Mat, Guangzhou 510275, Peoples R China
[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
[3] Hanshan Teachers Coll, Dept Chem, Chaozhou 521041, Guangdong, Peoples R China
关键词
cobalt; microporous; MOFs; imidazole-4,5-dicarboxylate; pillar; magnetismu;
D O I
10.1002/ejic.200501121
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
New three-dimensional, microporous metal-organic frameworks exhibiting reversible water adsorption, constructed from hexagonal [Co-3(imda)(2)] layers and N,N'-pillars, in which the dimensions of the channels are rationally adjustable by varying the lengths of pillars, have been designed, hydrothermally synthesized, and characterized. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006.
引用
收藏
页码:1931 / 1935
页数:5
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