Janus Polymer/Carbon Nanotube Hybrid Membranes for Oil/Water Separation

被引:312
作者
Gu, Jincui [1 ]
Xiao, Peng [1 ]
Chen, Jing [1 ]
Zhang, Jiawei [1 ]
Huang, Youju [1 ]
Chen, Tao [1 ]
机构
[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Div Polymer & Composite Mat, Ningbo 315201, Zhejiang, Peoples R China
关键词
Janus polymer/CNT membrane; SIPGP; superhydrophobic; hydrophilic; oil/water separation; WALLED CARBON NANOTUBES; BRUSHES; NANOSHEETS; SURFACE; ROBUST; FILMS; NANOPARTICLES; FABRICATION; GRAPHENE; REMOVAL;
D O I
10.1021/am504326m
中图分类号
TB3 [工程材料学];
学科分类号
082905 [生物质能源与材料];
摘要
A robust and simple method is provided to fabricate Janus polymer/carbon nanotube (CNT) hybrid membranes for oil/water separation. Starting from CNT membranes formed by dispensing, hydrophobic poly(styrene) (PS) and hydrophilic poly(N,N-dimethylaminoethyl methacrylate) (PDMAEMA) were grated from different sides of the photoactive CNT membranes via self-initiated photografting and photopolymerization (SIPGP) to achieve Janus polymer/CNTs hybrid membranes. The obtained membranes have excellent oil/water selectivity in the removal of oil from water. Moreover, they can effectively separate both surfactant-stabilized oil-in-water and water-in-oil emulsions because of the anisotropic wettability of the membranes.
引用
收藏
页码:16204 / 16209
页数:6
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