Design and synthesis of imidazolinium salts derived from (L)-valine. Investigation of their potential in chiral molecular recognition

被引：116

作者：

Clavier, H

Boulanger, L

Audic, N

Toupet, L

Mauduit, M ^{[1
]}

Guillemin, JC

机构：

[1] Ecole Natl Super Chim Rennes, Inst Chim Rennes, CNRS, UMR 6052, F-35700 Rennes, France

[2] Univ Rennes 1, CNRS, UMR 6626, F-35700 Rennes, France

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 10期

关键词：

D O I：

10.1039/b402368d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Several imidazolinium salts are synthesized from (L)-valine. A study of the structure relationships is achieved to obtain high diastereomeric interactions with an anionic substrate. High splitting up to 60 Hz of the (rac)-potassium Mosher's salt are observed by NMR spectroscopy.

引用

页码：1224 / 1225

页数：2

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