Ultrasonic enhancement of the supercritical extraction from ginger

被引:195
作者
Balachandran, S.
Kentish, S. E. [1 ]
Mawson, R.
Ashokkumar, M.
机构
[1] Univ Melbourne, Dept Chem & Biochem Engn, Cooperat Res Ctr Bioprod, Melbourne, Vic 3010, Australia
[2] Food Sci Australia, Werribee, Vic 3030, Australia
[3] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia
关键词
supercritical extraction; ultrasound; cavitation; mass transfer effects;
D O I
10.1016/j.ultsonch.2005.11.006
中图分类号
O42 [声学];
学科分类号
070206 ; 082403 ;
摘要
This work examines the concurrent use of power ultrasound during the extraction of pungent compounds from a typical herb (ginger) with supercritical CO2. A power ultrasonic transducer with an operating frequency of 20 kHz is connected to an extraction vessel and the extraction of gingerols from freeze-dried ginger particles (4-8 mm) is monitored. In the presence of ultrasound, we find that both the extraction rate and the yield increase. The higher extraction rate is attributed to disruption of the cell structures and an increase in the accessibility of the solvent to the internal particle structure, which enhances the intra-particle diffusivity. While cavitation would readily account for such enhancement in ambient processes, the absence of phase boundaries should exclude such phenomena above the critical point. Possible alternate. mechanisms for the cell structure damage are discussed. (C) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:471 / 479
页数:9
相关论文
共 28 条
[1]  
Adamson A., 2012, A textbook of physical chemistry
[2]   Ultrasound assisted chemical processes [J].
Ashokkumar, M ;
Grieser, F .
REVIEWS IN CHEMICAL ENGINEERING, 1999, 15 (01) :41-83
[3]  
BALACHANDRAN S, IN PRESS SEP PURIF T
[4]   OXIDATIVE-DEGRADATION OF PHENOL IN AQUEOUS-MEDIA USING ULTRASOUND [J].
BERLAN, J ;
TRABELSI, F ;
DELMAS, H ;
WILHELM, AM ;
PETRIGNANI, JF .
ULTRASONICS SONOCHEMISTRY, 1994, 1 (02) :S97-S102
[5]  
Brogle H., 1982, CHEM IND, V12, P385
[6]   Ultrasound-enhanced dissolution of UO2 in supercritical CO2 containing a CO2-philic complexant of tri-n-butylphosphate and nitric acid [J].
Enokida, Y ;
El-Fatah, SA ;
Wai, CM .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2002, 41 (09) :2282-2286
[7]   High-pressure sonoelectrochemistry in aqueous solution:: Soft cavitation under CO2 [J].
Goldfarb, DL ;
Corti, HR ;
Marken, F ;
Compton, RG .
JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (45) :8888-8893
[8]   Shrinking-core leaching model for supercritical-fluid extraction [J].
Goto, M ;
Roy, BC ;
Hirose, T .
JOURNAL OF SUPERCRITICAL FLUIDS, 1996, 9 (02) :128-133
[9]  
HICKS CP, 1975, CHEM REV, V75, P119, DOI 10.1021/cr60294a001
[10]  
KANDIAH M, 1990, INT J FOOD SCI TECH, V25, P328