Versatile Structure-Directing Roles of Deep-Eutectic Solvents and Their Implication in the Generation of Porosity and Open Metal Sites for Gas Storage

被引：216

作者：

Zhang, Jian ^{[1
]}

Wu, Tao ^{[2
]}

Chen, Shumei ^{[1
]}

Feng, Pingyun ^{[2
]}

Bu, Xianhui ^{[1
]}

机构：

[1] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA

[2] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 19期

关键词：

coordination modes; deep-eutectic solvents; ionic liquids; metal-organic frameworks; template synthesis; IONOTHERMAL SYNTHESIS; IONIC LIQUIDS; ORGANIC FRAMEWORKS; CHOLINE CHLORIDE/UREA; COORDINATION POLYMER; HYDROGEN STORAGE; MIXTURES; TEMPLATE;

D O I：

10.1002/anie.200900134

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Trap it in and burn it out: A deep-eutectic solvent provides a versatile medium for the creation of highly stable porous frameworks encapsulating neutral coordinating ligand molecules, which can escape intact from the pores upon heating to form crystals directly, leaving behind permanent porosity and coordinatively unsaturated metal sites with potential applications in gas storage and catalysis. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3486 / 3490

页数：5

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