Inverse spinel NiFeAlO4 as a highly active oxygen evolution electrocatalyst: promotion of activity by a redox-inert metal ion

被引：166

作者：

Chen, Jamie Y. C. ^{[1
]}

Miller, Jeffrey T. ^{[2
]}

Gerken, James B. ^{[1
]}

Stahl, Shannon S. ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

[2] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2014年 / 7卷 / 04期

关键词：

WATER OXIDATION; NICKEL FERRITE; COMBINATORIAL DISCOVERY; OXIDE CATALYSTS; LOW-TEMPERATURE; PHOTOSYSTEM-II; IRON; O-2; ELECTRODES; HYDROXIDE;

D O I：

10.1039/c3ee43811b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ni:Fe:Al mixed oxides were identified as highly active water oxidation electrocatalysts. A systematic investigation of these materials has led to the characterization of a well-defined NiFeAlO4 inverse spinel catalyst. Electrochemical characterization of NiFeAlO4 shows activity exceeding previously reported catalysts of similar composition and/or structure, including NiO, NiFe (9 : 1), and NiFe2O4.

引用

收藏

页码：1382 / 1386

页数：5

相关论文

共 57 条

[41] Electrocatalytic properties of spinel-type MnxFe3-x O-4 synthesized below 100 degrees C for oxygen evolution in KOH solutions [J].

Singh, NK ;

Tiwari, SK ;

Anitha, KL ;

Singh, RN .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (13) :2397-2400

[42]

Singh NK, 1999, INDIAN J CHEM A, V38, P491

[43] Effect of partial substitution of Cr on electrocatalytic properties of MnFe2O4 towards O2-evolution in alkaline medium [J].

Singh, R. N. ;

Singh, J. P. ;

Cong, H. Nguyen ;

Chartier, P. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2006, 31 (10) :1372-1378

[44] Electrocatalytic properties of new active ternary ferrite film anodes for O2 evolution in alkaline medium [J].

Singh, RN ;

Singh, NK ;

Singh, JP .

ELECTROCHIMICA ACTA, 2002, 47 (24) :3873-3879

[45] CATION DISTRIBUTIONS IN MIXED FERRITES [J].

SMART, JS .

PHYSICAL REVIEW, 1954, 94 (04) :847-850

[46] Water Oxidation Catalysis: Electrocatalytic Response to Metal Stoichiometry in Amorphous Metal Oxide Films Containing Iron, Cobalt, and Nickel [J].

Smith, Rodney D. L. ;

Prevot, Mathieu S. ;

Fagan, Randal D. ;

Trudel, Simon ;

Berlinguette, Curtis P. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (31) :11580-11586

[47] Oxygen Evolution Reaction Chemistry of Oxide-Based Electrodes [J].

Surendranath, Yogesh ;

Nocera, Daniel G. .

PROGRESS IN INORGANIC CHEMISTRY, VOL 57, 2012, 57 :505-560

[48] EXPGUI, a graphical user interface for GSAS [J].

Toby, BH .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2001, 34 :210-213

[49] Solution-Cast Metal Oxide Thin Film Electrocatalysts for Oxygen Evolution [J].

Trotochaud, Lena ;

Ranney, James K. ;

Williams, Kerisha N. ;

Boettcher, Shannon W. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (41) :17253-17261

[50]

Tsui EY, 2013, NAT CHEM, V5, P293, DOI [10.1038/nchem.1578, 10.1038/NCHEM.1578]

← 1 2 3 4 5 6 →