Linear and macrocyclic ruthenium(II) complexes containing bis(2,2′:6′,2"-terpyridine) ligands with flexible, naphthalene-centred spacers

被引：26

作者：

Chow, Hoi Shan ^{[1
]}

Constable, Edwin C. ^{[1
]}

Housecroft, Catherine E. ^{[1
]}

Neuburger, Markus ^{[1
]}

Schaffner, Silvia ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

POLYHEDRON | 2006年 / 25卷 / 08期

关键词：

metallomacrocycle; ruthenium(II); self-assembly; 2,2 ': 6 ',2 ''-terpyridine;

D O I：

10.1016/j.poly.2005.11.027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses and characterization of six ditopic ligands which contain polyethyleneoxy-substituted naphthalene spacers connecting two 2,2':6',2 ''-terpyridine metal-binding domains are described. The ligands, L, have been used to prepare two series of ruthenium(II) complexes: linear complexes of type [(tpy)Ru(L)Ru(tpy)](4+) were prepared as models for polymeric species, and metallomacrocyclic species [RunLn](2n+) (n = 2 or 3). Single crystal structures of a representative ligand and macrocyclic Ru(II) complex are reported. (C) 2005 Elsevier Ltd. All rights reserved.

引用

收藏

页码：1831 / 1843

页数：13

相关论文

共 53 条

[1] SIR92 - a program for automatic solution of crystal structures by direct methods [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, G ;

GUAGLIARDI, A ;

BURLA, MC ;

POLIDORI, G ;

CAMALLI, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435

[2] Metallo-polymerization/-cyclization of a C16-bridged di-terpyridine ligand and iron(II) ions [J].

Andres, PR ;

Schubert, US .

MACROMOLECULAR RAPID COMMUNICATIONS, 2004, 25 (15) :1371-1375

[3] Formation of metallo-polymers and -macrocycles by complexation of alkyl-linked di-terpyridines with iron(II) ions [J].

Andres, PR ;

Schubert, US .

SYNTHESIS-STUTTGART, 2004, (08) :1229-1238

[4] New functional polymers and materials based on 2,2′:6′,2"-terpyridine metal complexes [J].

Andres, PR ;

Schubert, US .

ADVANCED MATERIALS, 2004, 16 (13) :1043-1068

[5]

Armspach D, 1998, CHEM-EUR J, V4, P723, DOI 10.1002/(SICI)1521-3765(19980416)4:4<723::AID-CHEM723>3.0.CO

[6]

2-K

[7]

Armstrong SK, 2002, EUR J INORG CHEM, P141

[8] Recognition of bipyridinium-based derivatives by hydroquinone- and/or dioxynaphthalene-based macrocyclic polyethers: From inclusion complexes to the self-assembly of [2]catenanes [J].

Asakawa, M ;

Ashton, PR ;

Boyd, SE ;

Brown, CL ;

Gillard, RE ;

Kocian, O ;

Raymo, FM ;

Stoddart, JF ;

Tolley, MS ;

White, AJP ;

Williams, DJ .

JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (01) :26-37

[9] CRYSTALS version 12: software for guided crystal structure analysis [J].

Betteridge, PW ;

Carruthers, JR ;

Cooper, RI ;

Prout, K ;

Watkin, DJ .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2003, 36 :1487-1487

[10] Synthesis and electrochemical studies on a crown ether bearing a naphthoquinone acceptor [J].

Bond, AM ;

Ghiggino, KP ;

Hogan, CF ;

Hutchison, JA ;

Langford, SJ ;

Lygris, E ;

Paddon-Row, MN .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2001, 54 (12) :735-738

← 1 2 3 4 5 6 →