Ultrafast Click Conjugation of Macromolecular Building Blocks at Ambient Temperature

被引：198

作者：

Inglis, Andrew J. ^{[1
]}

Sinnwell, Sebastian ^{[1
]}

Stenzel, Martina H. ^{[2
]}

Barner-Kowollik, Christopher ^{[1
]}

机构：

[1] Univ Karlsruhe TH, Inst Tech Chem & Polymerchem, KIT, D-76128 Karlsruhe, Germany

[2] Univ New S Wales, CAMD, Sch Chem Sci & Engn, Sydney, NSW 2052, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 13期

关键词：

block copolymers; click chemistry; cycloaddition; polymerization; AZIDE-ALKYNE CYCLOADDITION; 3-ARM STAR POLYMERS; RAFT CHEMISTRY; COMBINATION; COPOLYMERS; TOOL; ACCESS; ROUTE; ATRP;

D O I：

10.1002/anie.200805993

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Block copolymers in seconds: Catalyst-free, ambient-temperature click conjugation of individual polymer strands becomes possible using novel ATRP-derived cyclopentadienylcapped polymers in an extremely rapid hetero-Diels-Alder cycloaddition with macromolecules equipped with electron-deficient dithioester end groups prepared by the RAFT process. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2411 / 2414

页数：4

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