Novel monovinyl methacrylic monomers containing secondary functionality for ultrarapid polymerization: Steady-state evaluation

被引:62
作者
Berchtold, KA
Nie, J
Stansbury, JW
Hacioglu, B
Beckel, ER
Bowman, CN [1 ]
机构
[1] Univ Colorado, Dept Chem Engn, Boulder, CO 80309 USA
[2] Los Alamos Natl Lab, Mat Sci & Technol Div, Los Alamos, NM 87545 USA
[3] Univ Colorado, Hlth Sci Ctr, Dept Restorat Dent, Denver, CO 80045 USA
关键词
D O I
10.1021/ma035862+
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Experimental investigations were made into the effects of monomer structure and functionality on free-radical polymerization kinetics. A more comprehensive understanding of how structural characteristics, monomer traits, and polymerization conditions influence the polymerization mechanisms and network evolution was desired. Variations in the nature of the monomers' secondary functionality and the terminal substitution were the primary variables examined. The three factors hypothesized as important to the advantageous polymerization characteristics observed are hydrogen bonding, hydrogen abstraction, and the electronic characteristics of the monomer. The experimental evaluations presented clearly demonstrate that each of these mechanisms contributes to the reactivity of these monomers and the networks that they form. The combination of these factors leads to crosslinked network formation and enhanced polymerization kinetics, i.e., monovinyl monomers with reactivities that rival those of commonly used divinyl monomers.
引用
收藏
页码:3165 / 3179
页数:15
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