Theoretical study of electronic relaxation processes in hydrated Gd3+ complexes in solutions

被引：27

作者：

Rast, S ^{[1
]}

Fries, PH

Belorizky, E

机构：

[1] CEA, Dept Rech Fondamentale Mat Condensee, Serv Chim Inorgan & Biol, Lab Reconnaissance Ion, F-38054 Grenoble 9, France

[2] Univ Grenoble 1, Spectrometrie Phys Lab, F-38402 St Martin Dheres, France

来源：

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE | 1999年 / 96卷 / 9-10期

关键词：

zero-field splitting; Redfield's relaxation theory; EPR line widths;

D O I：

10.1051/jcp:1999231

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The EPR line widths of [Gd(H2O)(8)](3+) measured in water at various magnetic fields by Merbach's group have been reinterpreted. A theoretical model of the transverse electronic relaxation is proposed, All the terms of the static zero-field splitting (ZFS) allowed by the symmetry of the complex are included and shown to have a significant contribution. The influence of a transient distortion ZFS is also studied.

引用

页码：1543 / 1550

页数：8

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