Recent advances and future aspects in the low-temperature conversion of saturated hydrocarbons

被引:15
作者
Akhmedov, VM [1 ]
Al-Khowaiter, SH [1 ]
机构
[1] Petr & Petrochem Res Inst, Riyadh 11442, Saudi Arabia
来源
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING | 2002年 / 44卷 / 03期
关键词
saturated hydrocarbons; low-temperature activation of C-H and C-C bonds; metal-complexes; supported metal-complexes derived from metal vapor; hydrocracking; isomerization; coupling of methane;
D O I
10.1081/CR-120005743
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A brief review on the advances and future aspects in the low-temperature activation of carbon-hydrogen and carbon-carbon bonds in hydrocarbons is presented. Particular attention is given to a catalyst formulation for low-temperature conversion of hydrocarbons. An efficient catalyst design method for low-temperature activation of saturated hydrocarbons has been worked out using metal evaporation techniques. The characteristic property of such catalysts is the presence of metal particles on the surface in an atomically dispersed state. Some of the prepared catalysts cause complete hydrocracking of alkanes and cycloalkanes at 423-463K.
引用
收藏
页码:455 / 498
页数:44
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