Lithium phosphorus oxynitride thin film fabricated by a nitrogen plasma-assisted deposition of E-beam reaction evaporation

被引:55
作者
Liu, WY [1 ]
Fu, ZW
Li, CL
Qin, QZ
机构
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[2] Fudan Univ, Laser Chem Inst, Shanghai Key Lab Mol Catalysts & Innovat Mat, Shanghai 200433, Peoples R China
关键词
D O I
10.1149/1.1778934
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Lithium phosphorus oxynitride (Lipon) thin films have been fabricated successfully by nitrogen plasma-assisted deposition of E-beam reactive evaporated Li3PO4 for the first time. The effect of inductively coupled plasma (ICP) powers on the electrical and optical properties of Lipon thin film was investigated. X-ray photoelectron spectra confirmed that the insertion of N into Li3PO4 and N concentration were dependent on ICP powers. Infrared and UV-vis spectrophotometry were used to characterize their optical properties. The electrical properties of the as-deposited Lipon thin films were investigated by impedance spectroscopy and isothermal transient ionic current measurements. (C) 2004 The Electrochemical Society.
引用
收藏
页码:J36 / J40
页数:5
相关论文
共 15 条
[1]   Diamond deposition and plasma diagnostics in a 27 MHz inductive coupled reactor (ICP) [J].
Awakowicz, P ;
Schwefel, R ;
Werder, M ;
Kasper, W .
DIAMOND AND RELATED MATERIALS, 1997, 6 (12) :1816-1823
[2]   Solid-state microbatteries for electronics in the 21st century [J].
Balkanski, M .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2000, 62 (1-2) :21-35
[3]   ELECTRICAL-PROPERTIES OF AMORPHOUS LITHIUM ELECTROLYTE THIN-FILMS [J].
BATES, JB ;
DUDNEY, NJ ;
GRUZALSKI, GR ;
ZUHR, RA ;
CHOUDHURY, A ;
LUCK, CF ;
ROBERTSON, JD .
SOLID STATE IONICS, 1992, 53 :647-654
[4]   FABRICATION AND CHARACTERIZATION OF AMORPHOUS LITHIUM ELECTROLYTE THIN-FILMS AND RECHARGEABLE THIN-FILM BATTERIES [J].
BATES, JB ;
DUDNEY, NJ ;
GRUZALSKI, GR ;
ZUHR, RA ;
CHOUDHURY, A ;
LUCK, CF ;
ROBERTSON, JD .
JOURNAL OF POWER SOURCES, 1993, 43 (1-3) :103-110
[5]  
Fowles G. R., 1975, INTRO MODERN OPTICS
[6]   Dielectric and Li transport properties of electron conducting and non-conducting sputtered amorphous Ta2O5 films [J].
Frenning, G ;
Nilsson, M ;
Westlinder, J ;
Niklasson, GA ;
Mattsson, MS .
ELECTROCHIMICA ACTA, 2001, 46 (13-14) :2041-2046
[7]   Lithium ion diffusion behavior in laser-deposited TiO2 films [J].
Fu, ZW ;
Qin, QZ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (23) :5505-5510
[8]   Structural study of amorphous vanadium oxide films for thin film microbattery [J].
Kim, HK ;
Seong, TY ;
Yoon, YS .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2003, 21 (02) :754-759
[9]  
Pankove J., 1975, OPTICAL PROCESSES SE
[10]   PREPARATION AND PROPERTIES OF AMORPHOUS PHOSPHORUS NITRIDE PREPARED IN A LOW-PRESSURE PLASMA [J].
VEPREK, S ;
IQBAL, Z ;
BRUNNER, J ;
SCHARLI, M .
PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 1981, 43 (03) :527-547