A novel system consisting of easily recyclable dendritic Ru-BINAP catalyst for asymmetric hydrogenation

被引:84
作者
Deng, GJ
Fan, QH [1 ]
Chen, XM
Liu, DS
Chan, ASC
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
[2] Hong Kong Polytech Univ, Open Lab Chirotechnol, Hong Kong, Hong Kong, Peoples R China
[3] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China
关键词
D O I
10.1039/b203117e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Dendritic Ru-BINAP catalysts functionalized with alkyl chain at the periphery together with organic binary solvent system that exhibited phase separation induced by addition of a little water have been employed for asymmetric hydrogenation, leading to high catalytic activity and enantioselectivity as well as facile catalyst recycling.
引用
收藏
页码:1570 / 1571
页数:2
相关论文
共 29 条
[1]  
Abatjoglou AG, 1996, CHEM INDUST, V68, P133
[2]   Dendritic catalysts and dendrimers in catalysis [J].
Astruc, D ;
Chardac, F .
CHEMICAL REVIEWS, 2001, 101 (09) :2991-3023
[3]   Homogeneous catalysis - Toward greener chemistry [J].
Baker, RT ;
Tumas, W .
SCIENCE, 1999, 284 (5419) :1477-1479
[4]   Preparation and use of a polymer supported BINAP hydrogenation catalyst [J].
Bayston, DJ ;
Fraser, JL ;
Ashton, MR ;
Baxter, AD ;
Polywka, MEC ;
Moses, E .
JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (09) :3137-3140
[5]   Palladium-catalyzed C-C coupling under thermomorphic conditions [J].
Bergbreiter, DE ;
Osburn, PL ;
Wilson, A ;
Sink, EM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (38) :9058-9064
[6]   Nonpolar polymers for metal sequestration and ligand and catalyst recovery in thermomorphic systems [J].
Bergbreiter, DE ;
Osburn, PL ;
Frels, JD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (44) :11105-11106
[7]  
Breinbauer R, 2000, ANGEW CHEM INT EDIT, V39, P3604, DOI 10.1002/1521-3773(20001016)39:20<3604::AID-ANIE3604>3.0.CO
[8]  
2-9
[9]   Asymmetric hydrogenation and catalyst recycling using ionic liquid and supercritical carbon dioxide [J].
Brown, RA ;
Pollet, P ;
McKoon, E ;
Eckert, CA ;
Liotta, CL ;
Jessop, PG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (06) :1254-1255
[10]   Dendritic catalysts for asymmetric transfer hydrogenation [J].
Chen, YC ;
Wu, TF ;
Deng, JG ;
Liu, H ;
Jiang, YZ ;
Choib, MCK ;
Chan, ASC .
CHEMICAL COMMUNICATIONS, 2001, (16) :1488-1489