Room temperature synthesis in liquid ammonia of zinc, cadmium, and mercury sulfides

被引：7

作者：

Hector, AL ^{[1
]}

Henshaw, G ^{[1
]}

Parkin, IP ^{[1
]}

Shaw, GA ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,DEPT CHEM,LONDON WC1H 0AJ,ENGLAND

来源：

MAIN GROUP CHEMISTRY | 1996年 / 1卷 / 02期

关键词：

D O I：

10.1080/13583149612331338415

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of elemental zinc, cadmium, or mercury with sulfur in liquid ammonia at room temperature produces X-ray amorphous metal sulfide MS (M = Zn, Cd, Hg). Thermolysis of this material at 250-300 degrees C produced crystalline MS(alpha-ZnS (wurtzite), alpha-CdS (greenockite), alpha-HgS (cinnabar), and beta-HgS (metacinnabar). Products were characterised by microanalysis, ET-IR and Raman spectroscopy, SEM/EDAX, X-ray powder diffraction, magnetic moment measurements, and X-ray photoelectron spectroscopy.

引用

页码：183 / 187

页数：5

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