Polymerisation of olefins catalysed by a palladium complex in supercritical carbon dioxide

被引：32

作者：

de Vries, TJ

Duchateau, R

Vorstman, MAG

Keurentjes, JTF

机构：

[1] Eindhoven Univ Technol, Dept Chem & Chem Engn, Proc Dev Grp, NL-5600 MB Eindhoven, Netherlands

[2] Dutch Polymer Inst, NL-5600 AX Eindhoven, Netherlands

[3] Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 04期

关键词：

D O I：

10.1039/a908966g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A late transition metal catalyst has been used to polymerise hex-1-ene and ethene in supercritical carbon dioxide, yielding high molecular weight polymers; a comparison with polymerisations in CH2Cl2 reveal that polymers with identical molecular weight and polydispersity are formed.

引用

页码：263 / 264

页数：2

共 13 条

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