Evaluation of fuel cell system efficiency and degradation at development and during commercialization

被引:58
作者
Gemmen, R. S. [1 ]
Johnson, C. D. [1 ]
机构
[1] Natl Energy Technol Lab, Morgantown, WV 26507 USA
关键词
degradation; fuel cell; system; standards; PART I; TEMPERATURE;
D O I
10.1016/j.jpowsour.2005.10.109
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Two primary parameters stand out for characterizing fuel cell system performance. The first and most important parameter is system efficiency. This parameter is relatively easy to define, and protocols for its assessment are already available. Another important parameter yet to be fully considered is system degradation. Degradation is important because customers desire to know how long their purchased fuel cell unit will last. The measure of degradation describes this performance factor by quantifying, for example, how the efficiency of the unit degrades over time. While both efficiency and degradation concepts are readily understood, the coupling between these two parameters must also be understood so that proper testing and evaluation of fuel cell systems is achieved. Tests not properly performed, and results not properly understood, may result in improper use of the evaluation data, producing improper R&D planning decisions and financial investments. This paper presents an analysis of system degradation, recommends an approach to its measurement, and shows how these two parameters are related and how one can be "traded-off" for the other. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:646 / 655
页数:10
相关论文
共 26 条
[1]  
ABENS S, 2000, AES 2000 ALL EL SHIP
[2]   A solid oxide fuel cell operating on hydrogen sulfide (H2S) and sulfur-containing fuels [J].
Aguilar, L ;
Zha, SW ;
Cheng, Z ;
Winnick, J ;
Liu, ML .
JOURNAL OF POWER SOURCES, 2004, 135 (1-2) :17-24
[3]  
CHEN W, IN PRESS ELECTROCHIM
[4]   Chemical degradation of La1-xSrMnO3/Y2O3-stabilized ZrO2 composite cathodes in the presence of current collector pastes [J].
Chervin, C ;
Glass, RS ;
Kauzlarich, SM .
SOLID STATE IONICS, 2005, 176 (1-2) :17-23
[5]  
ETEMAD S, 2003, P 2003 DISTRIBUTED E
[6]   Incorporation of voltage degradation into a generalised steady state electrochemical model for a PEM fuel cell [J].
Fowler, MW ;
Mann, RF ;
Amphlett, JC ;
Peppley, BA ;
Roberge, PR .
JOURNAL OF POWER SOURCES, 2002, 106 (1-2) :274-283
[7]  
GEMMEN RS, 1998, 1998 IJPGC BALT MD A
[8]   Degradation of the electrical conductivity in stabilised zirconia systems Part I: yttria-stabilised zirconia [J].
Haering, C ;
Roosen, A ;
Schichl, H .
SOLID STATE IONICS, 2005, 176 (3-4) :253-259
[9]   Statistical geometry of reaction space in porous cermet anodes based on ion-conducting electrolytes - Patterns of degradation [J].
Ioselevich, A ;
Kornyshev, AA ;
Lehnert, W .
SOLID STATE IONICS, 1999, 124 (3-4) :221-237
[10]  
KIMBALL JW, 2004, POWER ELECT TECH OCT