Hydrothermal functionalisation of single-walled carbon nanotubes

被引：37

作者：

Duesberg, GS

Graupner, R

Downes, P

Minett, A

Ley, L

Roth, S

Nicoloso, N

机构：

[1] Infineon Technol AG, Corp Res, D-81739 Munich, Germany

[2] Univ Erlangen Nurnberg, Inst Tech Phys, D-91058 Erlangen, Germany

[3] Trinity Coll Dublin, Dept Mat Sci, Dublin 2, Ireland

[4] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany

[5] Deutsch Zentrum Luft & Raumfahrt, DLR, ITT, D-70569 Stuttgart, Germany

来源：

SYNTHETIC METALS | 2004年 / 142卷 / 1-3期

关键词：

nanotubes; functionalisation; hydrothermal treatment;

D O I：

10.1016/j.synthmet.2003.09.009

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Chemical functionalisation of single-walled carbon nanotubes (SWNTs) has been achieved by hydrothermal treatment (HT) in aqueous acidic solutions. Depending on the type of acid chlorine, bromine or sulphur could be attached to the conjugated pi-system. Apart from the well known effects of acid oxidation, X-ray and ultraviolet photoemission spectroscopy suggest that the halides are introduced at structurally/electronically disordered defect sites. Sulphur is incorporated in higher density, probably in a similar fashion as oxygen. HT thus provides an efficient tool to functionalise SWNTs and paves the way for new SWNT materials and synthetic routes in various polar media and electrolytes. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：263 / 266

页数：4

共 22 条

[1] Work functions and surface functional groups of multiwall carbon nanotubes [J].

Ago, H ;

Kugler, T ;

Cacialli, F ;

Salaneck, WR ;

Shaffer, MSP ;

Windle, AH ;

Friend, RH .

JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (38) :8116-8121

[2] Workfunction of purified and oxidised carbon nanotubes [J].

Ago, H ;

Kugler, T ;

Cacialli, F ;

Petritsch, K ;

Friend, RH ;

Salaneck, WR ;

Ono, Y ;

Yamabe, T ;

Tanaka, K .

SYNTHETIC METALS, 1999, 103 (1-3) :2494-2495

[3] Carbon nanotubes - the route toward applications [J].

Baughman, RH ;

Zakhidov, AA ;

de Heer, WA .

SCIENCE, 2002, 297 (5582) :787-792

[4]

Beamson G., 1992, ADV MATER, DOI DOI 10.1002/ADMA.19930051035

[5] Origin of the Breit-Wigner-Fano lineshape of the tangential G-band feature of metallic carbon nanotubes -: art. no. 155414 [J].

Brown, SDM ;

Jorio, A ;

Corio, P ;

Dresselhaus, MS ;

Dresselhaus, G ;

Saito, R ;

Kneipp, K .

PHYSICAL REVIEW B, 2001, 63 (15)

[6] Solution properties of single-walled carbon nanotubes [J].

Chen, J ;

Hamon, MA ;

Hu, H ;

Chen, YS ;

Rao, AM ;

Eklund, PC ;

Haddon, RC .

SCIENCE, 1998, 282 (5386) :95-98

[7] Interconnection of carbon nanotubes by chemical functionalization [J].

Chiu, PW ;

Duesberg, GS ;

Dettlaff-Weglikowska, U ;

Roth, S .

APPLIED PHYSICS LETTERS, 2002, 80 (20) :3811-3813

[8] Use of XPS in the determination of chemical environment and oxidation state of iron and sulfur samples: constitution of a data basis in binding energies for Fe and S reference compounds and applications to the evidence of surface species of an oxidized pyrite in a carbonate medium [J].

Descostes, M ;

Mercier, F ;

Thromat, N ;

Beaucaire, C ;

Gautier-Soyer, M .

APPLIED SURFACE SCIENCE, 2000, 165 (04) :288-302

[9] Modification of single-walled carbon nanotubes by hydrothermal treatment [J].

Duesberg, GS ;

Roth, S ;

Downes, P ;

Minett, A ;

Graupner, R ;

Ley, L ;

Nicoloso, N .

CHEMISTRY OF MATERIALS, 2003, 15 (17) :3314-3319

[10] Towards processing of carbon nanotubes for technical applications [J].

Duesberg, GS ;

Muster, J ;

Byrne, HJ ;

Roth, S ;

Burghard, M .

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1999, 69 (03) :269-274

← 1 2 3 →