Line intensity of R(0) and R(3) of the 12CH4 2ν3 band from diode laser spectroscopy

被引：27

作者：

Hurtmans, D

Dufour, G

Bell, W

Henry, A

Valentin, A

Camy-Peyret, C

机构：

[1] Free Univ Brussels, Lab Chim Phys Mol, B-1050 Brussels, Belgium

[2] Univ Paris 06, Lab Phys Mol & Applicat, CNRS, F-75252 Paris 05, France

[3] Natl Phys Lab, Teddington TW11 0LW, Middx, England

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 2002年 / 215卷 / 01期

关键词：

D O I：

10.1006/jmsp.2002.8620

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

We have determined the spectroscopic parameters that are necessary to describe accurately the R(0) line profile of the CH(4)2nu(3) band from about 1 Torr to a few hundred Torr of pure CH4. The intensities determined at each pressure are in overall agreement to better than 0.7%. The R(3) manifold of the same band has also been investigated. Relative positions and absolute intensities of the three transitions composing the triplet have been determined. The intensity distribution inside the triplet is in fair agreement with recent theoretical predictions, (C) 2002 Elsevier Science (USA).

引用

页码：128 / 133

页数：6

共 15 条

[1]

CHAMPION JP, 2002, COMMUNICATION

[2]

CLAVEAU C, 2002, SPECTROCHIM ACTA A

[3] Atmospheric CH4 and H2O monitoring with near-infrared InGaAs laser diodes by the SDLA, a balloonborne spectrometer for tropospheric and stratospheric in situ measurements [J].