Chiral phosphinooxathiane ligands for catalytic asymmetric Diels-Alder reaction

被引：41

作者：

Nakano, H

Suzuki, Y

Kabuto, C

Fujita, R

Hongo, H

机构：

[1] Tohoku Pharmaceut Univ, Aoba Ku, Sendai, Miyagi 9818558, Japan

[2] Tohoku Univ, Grad Sch Sci, Instrumental Anal Ctr Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 67卷 / 14期

关键词：

D O I：

10.1021/jo0201474

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral cationic palladium-phosphinooxathiane complexes have been found to be effective catalysts for enantioselective Diels-Alder (DA) reaction of cyclopentadiene with acyl-1,3-oxazolidin-2-ones to give the corresponding DA adducts in good yield and high enantioselectivity up to 93% ee.

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页码：5011 / 5014

页数：4

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