Kinetic behaviour of electrochemical potential in three-phase heterogeneous catalytic oxidation reactions

被引：22

作者：

Tokarev, Anton V. ^{[1
]}

Murzina, Elena V. ^{[1
]}

Kuusisto, Jyrki ^{[1
]}

Mikkola, Jyri-Pekka ^{[1
]}

Eranen, Kari ^{[1
]}

Murzin, Dmitry Yu. ^{[1
]}

机构：

[1] Abo Akad Univ, FIN-20500 Turku, Finland

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2006年 / 255卷 / 1-2期

关键词：

electrochemical catalyst potential; pH effects; Pd; aldehyde oxidation; in situ technique;

D O I：

10.1016/j.molcata.2006.04.014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Kinetic behaviour of catalyst electrochemical potential was studied during three-phase heterogeneous reaction Of D-lactose oxidation. The influence of different factors on in situ measured catalyst electrochemical potential is considered. A kinetic model capable to explain transient behaviour of catalyst electrochemical potential at different conditions such as conversion, oxygen partial pressure, temperature and pH is proposed. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：199 / 208

页数：10

共 31 条

[1]

[Anonymous], 2005, ENZYMATIC KINETICS

[2] Selective oxidation of alcohols and aldehydes on metal catalysts [J].