Coulombic effects in radical-cation-based high-spin polymers

被引：9

作者：

Bushby, RJ

McGill, DR

Ng, KM

Taylor, N

机构：

[1] School of Chemistry, University of Leeds, Leeds

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 23期

关键词：

D O I：

10.1039/cc9960002641

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A comparison of the cyclic voltammetric behaviour of a high-spin polymer precursor having the local topology of a 3,4'-diaminobiphenyl with that of related oligomers shows that the hole-hole repulsion associated with the coextensive spin-spin distribution is < 0.2 V, a noticeable effect but not one large enough to explain the difficulty of doping these polymers.

引用

页码：2641 / 2642

页数：2

共 19 条

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