Platinum catalysed 3,4- and 1,4-diboration of α,β-unsaturated carbonyl compounds using bis-pinacolatodiboron

被引：114

作者：

Bell, NJ

Cox, AJ

Cameron, NR

Evans, JSO

Marder, TB

Duin, MA

Elsevier, CJ

Baucherel, X

Tulloch, AAD

Tooze, RP

机构：

[1] Univ Durham, Dept Chem, Univ Sci Labs, Durham DH1 3LE, England

[2] Univ Amsterdam, Vant Hoff Inst Mol Chem, NL-1018 Amsterdam, Netherlands

[3] Johnson Matthey Catalysts, Billingham TS23 1LB, Cleveland, England

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 16期

关键词：

D O I：

10.1039/b406052k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis-pinacolatodiboron reacts with alpha,beta-unsaturated carbonyl compounds to give 1,4- and unprecedented 3,4-additions in the presence of a second generation Pt(0) catalyst at ambient temperature.

引用

页码：1854 / 1855

页数：2

共 26 条

[1]

Ali H. A., 2001, ORGANOMETALLICS, V20, P3962

[2] TRANSITION-METAL-CATALYZED DIBORATION OF VINYLARENES [J].

BAKER, RT ;

NGUYEN, P ;

MARDER, TB ;

WESTCOTT, SA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (12) :1336-1338

[3] Rhodium catalysed diboration of unstrained internal alkenes and a new and general route to zwitterionic [L2Rh(η6-catBcat)] (cat = 1,2-O2C6H4) complexes [J].

Dai, CY ;

Robins, EG ;

Scott, AJ ;

Clegg, W ;

Yufit, DS ;

Howard, JAK ;

Marder, TB .

CHEMICAL COMMUNICATIONS, 1998, (18) :1983-1984

[4] A novel and highly regioselective Cr-mediated route to functionalised quinone boronic ester derivatives [J].

Davies, MW ;

Johnson, CN ;

Harrity, JPA .

CHEMICAL COMMUNICATIONS, 1999, (20) :2107-2108

[5] Synthesis of novel quinone boronic ester derivatives via a highly regioselective Cr-mediated benzannulation reaction and their application in Pd-catalyzed coupling processes [J].

Davies, MW ;

Johnson, CN ;

Harrity, JPA .

JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (10) :3525-3532

[6] CONJUGATE REDUCTION OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS BY CATECHOLBORANE [J].

EVANS, DA ;

FU, GC .

JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (22) :5678-5680

[7] METAL-PROMOTED INSERTION OF AN ACTIVATED ALKENE INTO A B-H BOND OF AN EXOPOLYHEDRAL NIDO-RHODACARBORANE - RHODIUM-CATALYZED HYDROBORATION [J].

HEWES, JD ;

KREIMENDAHL, CW ;

MARDER, TB ;

HAWTHORNE, MF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (19) :5757-5759

[8] CHLOROBORATION AND ALLIED REACTIONS OF UNSATURATED COMPOUNDS .9. ORGANOMETALLIC INSERTION REACTIONS OF DIKETEN - SYNTHESIS OF BETA-KETO-ENOLATES [J].

HORDER, JR ;

LAPPERT, MF .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (02) :173-&

[9] Synthesis and antifungal and antibacterial bioactivity of cyclic diamines containing boronate esters [J].

Irving, AM ;

Vogels, CM ;

Nikolcheva, LG ;

Edwards, JP ;

He, XF ;

Hamilton, MG ;

Baerlocher, MO ;

Baerlocher, FJ ;

Decken, A ;

Westcott, SA .

NEW JOURNAL OF CHEMISTRY, 2003, 27 (10) :1419-1424

[10] Diboration of alkenes with bis(pinacolato)diboron catalysed by a platinum(0) complex [J].

Ishiyama, T ;

Yamamoto, M ;

Miyaura, N .

CHEMICAL COMMUNICATIONS, 1997, (07) :689-690

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