eta(3)-, eta(4)- eta(6)-Co-ordination complexes of the weakly co-ordinating anion tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

被引：39

作者：

Powell, J

Lough, A

Saeed, T

机构：

[1] Department of Chemistry, University of Toronto, Toronto

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 22期

关键词：

D O I：

10.1039/a706044k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single-crystal X-ray diffraction has established eta(3)-, eta(4)- and eta(6)- co-ordination of the anion tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (TFPB) in the complexes Ag(TFPB)(2,2'-bipy) (2,2'-bipy = 2,2'-bipyridine), Ag(TFPB)(1,2-C6H4I2) and Rh(TFPB)(cod) (cod = cycloocta-1,5-diene) respectively.

引用

页码：4137 / 4138

页数：2

共 9 条

[1]

Aresta M, 1997, NEW J CHEM, V21, P595

[2] Syntheses and structures of alkyl and aryl halide complexes of the type [(PiPr(3))(2)PtH(eta(1)-XR)]BArf and analogues with Et(2)O, THF, and H-2 ligands. Halide-to-metal pi bonding in halocarbon complexes [J].