New, highly acidic ionic liquid systems and their application in the carbonylation of toluene

被引：56

作者：

Brausch, N ^{[1
]}

Metlen, A ^{[1
]}

Wasserscheid, P ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Lehrstuhl Chem Reaktionstech, D-91058 Erlangen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 13期

关键词：

D O I：

10.1039/b403464c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Based on the surprisingly high solubility of AlCl3 in ionic liquids of type [cation] [(CF3SO2)(2)N], a new class of highly acidic, ionic systems has been developed. First tests in toluene carbonylation revealed high potential of these new acidic ionic liquids as catalyst for arene functionaliziation reactions.

引用

页码：1552 / 1553

页数：2

共 15 条

[1] Hydrophobic, highly conductive ambient-temperature molten salts [J].

Bonhote, P ;

Dias, AP ;

Papageorgiou, N ;

Kalyanasundaram, K ;

Gratzel, M .

INORGANIC CHEMISTRY, 1996, 35 (05) :1168-1178

[2]

EARLE M, 2003, IONIC LIQUIDS SYNTHE

[3] PROPERTIES OF 1,3-DIALKYLIMIDAZOLIUM CHLORIDE ALUMINUM-CHLORIDE IONIC LIQUIDS .2. PHASE-TRANSITIONS, DENSITIES, ELECTRICAL CONDUCTIVITIES, AND VISCOSITIES [J].

FANNIN, AA ;

FLOREANI, DA ;

KING, LA ;

LANDERS, JS ;

PIERSMA, BJ ;

STECH, DJ ;

VAUGHN, RL ;

WILKES, JS ;

WILLIAMS, JL .

JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (12) :2614-2621

[4]

HERBST K, Patent No. 2003181780

[5] THE ELECTRODEPOSITION OF ALUMINUM FROM NONAQUEOUS SOLUTIONS AT ROOM TEMPERATURE [J].

HURLEY, FH ;

WIER, TP .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1951, 98 (05) :207-212

[6] An ionic liquid mediated Friedel-Crafts addition of arenes to isothiocyanates [J].

Naik, PU ;

Nara, SJ ;

Harjani, JR ;

Salunkhe, MM .

CANADIAN JOURNAL OF CHEMISTRY, 2003, 81 (10) :1057-1060

[7] Ionic liquids: perspectives for organic and catalytic reactions [J].

Olivier-Bourbigou, H ;

Magna, L .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 182 (01) :419-437

[8]

RORSYTH SA, 2004, AUST J CHEM, V57, P113

[9]

SALEH R, Patent No. 2000015594

[10] Oligomerization of olefins in a chloroaluminate ionic liquid [J].

Stenzel, O ;

Brüll, R ;

Wahner, UM ;

Sanderson, RD ;

Raubenheimer, HG .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 192 (1-2) :217-222

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