Structural Aspects of 1,3,5-Benzenetrisamides-A New Family of Nucleating Agents

被引:50
作者
Kristiansen, Magnus [1 ]
Smith, Paul [1 ]
Chanzy, Henri [2 ]
Baerlocher, Christian [1 ]
Gramlich, Volker [1 ]
McCuskcr, Lynne [1 ]
Weber, Thomas [1 ]
Pattison, Philip [3 ,4 ]
Blomenhofer, Markus [5 ]
Schmidt, Hans-Werner [5 ]
机构
[1] ETH, Dept Mat, CH-8093 Zurich, Switzerland
[2] CNRS, Ctr Rech Macromol Vegetales, F-38041 Grenoble 9, France
[3] European Synchrotron Radiat Facil, F-38043 Grenoble, France
[4] Ecole Polytech Fed Lausanne, Crystallog Lab, CH-1015 Lausanne, Switzerland
[5] Univ Bayreuth, Bayreuther Inst Makromol Forsch, D-95440 Bayreuth, Germany
关键词
ISOTACTIC POLYPROPYLENE; MESOMORPHIC COMPOUNDS; ALPHA-PHASE; CRYSTALLIZATION; BEHAVIORS;
D O I
10.1021/cg900139d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Structural studies of substituted 1,3,5-benzenetrisamides, a new family of highly versatile and efficient nucleating and clarifying agents for polymeric materials, are reported. Subtle details of the molecular structure of these species are shown to have a major influence on their solid-state order, morphology, and ability to nucleate specific polymorphs of isotactic polypropylene and induce a broad spectrum of useful mechanical and optical properties in the latter material.
引用
收藏
页码:2556 / 2558
页数:3
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