Microstructural investigations of nanostructured La(Sr)MnO3-δ films deposited by electrostatic spray deposition

被引:45
作者
Princivalle, A [1 ]
Perednis, D [1 ]
Neagu, R [1 ]
Djurado, E [1 ]
机构
[1] Inst Natl Polytech Grenoble, ENSEEG, Lab Electrochim & Physicochim Mat & Interfaces, F-38402 St Martin Dheres, France
关键词
D O I
10.1021/cm049158z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The deposition of (La0.85Sr0.15)(0.95)MnO3-delta films on an yttria-stabilized zirconia substrate was studied by the electrostatic spray deposition (ESD) technique. Films with various morphologies were obtained. The surface morphology was strongly influenced by the precursor solution flow rate and deposition temperature. Processes involved in the porous film formation were discussed. Powder X-ray diffraction analysis showed that the LSM hexagonal phase was formed and was nanostructured, consisting of crystallites of 60-75 nm on average, after thermal treatment ranging from 600 to 900 degreesC.
引用
收藏
页码:3733 / 3739
页数:7
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