Synthesis of Bis(imino)pyridine Iron Amide and Ammonia Compounds from an N-H Transfer Agent

被引：29

作者：

Bowman, Amanda C. ^{[2
]}

Bart, Suzanne C. ^{[1
,2
]}

Heinemann, Frank W. ^{[1
]}

Meyer, Karsten ^{[1
]}

Chirik, Paul J. ^{[2
]}

机构：

[1] Univ Erlangen Nurnberg, Dept Chem & Pharm, D-91058 Erlangen, Germany

[2] Cornell Univ, Baker Lab, Dept Chem & Chem Biol, Ithaca, NY 14853 USA

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 13期

关键词：

NEUTRAL-LIGAND COMPLEXES; HYDROGENATION; REACTIVITY; CHEMISTRY; VALENT; IMIDE;

D O I：

10.1021/ic9003017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Addition of the [NH] transfer reagent Hdbabh (dbabh = 2,3:5,6-dibenzo-7-azabicyclo[2.2.1]hepta-2,5-diene) to the bis(imino)pyridine iron bis(dinitrogen) complex, ((PDI)-P-iPr)Fe(N-2)(2) ((PDI)-P-iPr = 2,6-(2,6-(Pr2C6H3N)-Pr-i=CMe)(2)C5H3N), furnished the corresponding iron amide and ammonia compounds, resulting from cleavage of the strained amine. Isotopic labeling studies support N-H bond activation by a transient, parent imide, [((PDI)-P-iPr)FeNH].

引用

页码：5587 / 5589

页数：3

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