Heterogeneous catalytic transformations for environmentally friendly production

被引:342
作者
Sheldon, RA [1 ]
Downing, RS [1 ]
机构
[1] Delft Univ Technol, Organ Chem & Catalysis Lab, NL-2628 BJ Delft, Netherlands
关键词
environment; fine chemicals; heterogeneous catalysis; solid acid; solid base; redox catalysis; zeolite;
D O I
10.1016/S0926-860X(99)00274-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Progress towards environmentally responsible processing is marked by the elimination of waste and by-product generation and reduced dependence on hazardous chemicals. The key to both is often provided by catalytic as alternatives to stoichiometric processes. Heterogeneous catalysis,long established in bulk-chemicals processing, is beginning to make inroads into the fine-chemicals industry also. This tendency is helped by the availability of novel catalytic materials and modern techniques of creating and investigating specific active sites on catalyst surfaces. In this overview, examples from the areas of acid/base and redox catalysis are chosen to illustrate the trend from non-catalytic to catalytic processes. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:163 / 183
页数:21
相关论文
共 94 条
  • [1] ALTMAN LJ, 1991, Patent No. 5001283
  • [2] [Anonymous], 1990, CHIM IND MILAN
  • [3] Oxidative transformations of organic compounds mediated by redox molecular sieves
    Arends, IWCE
    Sheldon, RA
    Wallau, M
    Schuchardt, U
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (11) : 1144 - 1163
  • [4] BAIKER A, 1997, HDB HETEROGENEOUS CA, V5, P2422
  • [5] BASSET JM, 1998, 9 INT S REL HOM HET, P1
  • [6] BELLOCQ N, 1998, SUPPORTED REAGENTS C, P162
  • [7] VAPOR-PHASE NITRATION OF BENZENE OVER MODIFIED MORDENITE CATALYSTS
    BERTEA, L
    KOUWENHOVEN, HW
    PRINS, R
    [J]. APPLIED CATALYSIS A-GENERAL, 1995, 129 (02) : 229 - 250
  • [8] Chang C. D., 1980, US, Patent No. [4,220,783, 4220783]
  • [9] CHANG CD, 1983, Patent No. 82613
  • [10] SHAPE-SELECTIVE ALKYLATION OF NAPHTHALENE WITH ISOPROPANOL OVER LARGE-PORE ZEOLITES
    CHU, SJ
    CHEN, YW
    [J]. APPLIED CATALYSIS A-GENERAL, 1995, 123 (01) : 51 - 58