Water-soluble organometallic catalysts from carbohydrates. 1. diphosphinite-Rh complexes

被引：49

作者：

Shin, S ^{[1
]}

RajanBabu, TV ^{[1
]}

机构：

[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA

来源：

ORGANIC LETTERS | 1999年 / 1卷 / 08期

关键词：

D O I：

10.1021/ol9908979

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Cyclohexylidene-protected diphosphinite-Rh complex A derived from alpha,alpha'-trehalose was treated with acidic resin in methanol to get the unprotected complex B, which is water soluble. Preparation of complexes A-C and their applications for hydrogenations show the problems and prospects of using water as a solvent for these reactions.

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页码：1229 / 1232

页数：4

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