Structure of zinc hydroxy-terephthalate:: Zn3(OH)4(C8H4O4)

被引：23

作者：

Carton, Anne

Abdelouhab, Sandra

Renaudin, Guillaume

Rabu, Pierre

Francois, Michel

机构：

[1] Univ Nancy 1, Fac Sci, Lab Chim Solide Minerale, UMR 7555, F-54506 Vandoeuvre Les Nancy, France

[2] Univ Clermont Ferrand, Lab Mat Inorgan, CNRS, UMR 6002, F-63177 Clermont Ferrand, France

[3] CNRS, Inst Phys & Chim Mat Strasbourg, UMR 75040, F-67037 Strasbourg, France

来源：

SOLID STATE SCIENCES | 2006年 / 8卷 / 08期

关键词：

zinc hydroxide; hybrid lamellar; layered material;

D O I：

10.1016/j.solidstatesciences.2006.02.043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new lamellar hydroxide teraphthalate Zn-3(OH)(4)(C8H4O4) was synthesised by the hydrothermal method and was characterized by single crystal X-ray diffraction, IR and UV spectroscopy and thermogravimetric analysis. The compound crystallises in the monoclinic space group C2/c with: a = 28.1000(5) angstrom, b = 6.3101 (1) angstrom, c = 14.359(3) angstrom, P = 121.564(1)degrees, V = 2241.43 angstrom(3), Dx = 2.538 g/cm(3) and Z = 4. The zinc(II) atoms present four, five and six fold O-coordination. Due to the peculiar coordination of the zinc atoms, the inorganic layers form stairways running along [001]. These stairways-like layers are bridged by tereplithalate (tp) groups leading to a 3D framework. (c) 2006 Elsevier SAS. All rights reserved.

引用

页码：958 / 963

页数：6

共 33 条

[1] Ab initio crystal structure of copper(II) hydroxy-terephthalate by synchrotron powder diffraction and magnetic properties [J].